| dc.contributor.author | Orishaba, Donitar | |
| dc.date.accessioned | 2021-05-10T06:43:05Z | |
| dc.date.available | 2021-05-10T06:43:05Z | |
| dc.date.issued | 2019-08-30 | |
| dc.identifier.citation | Orishaba, D. (2019). Synthesis, characterization of stable cyano, thiocyanate bridged complexes and Polyoxometalate Inorganic fragments.(Unpublished Undergraduat thesis ) . Makerere University. Kampala Uganda. | en_US |
| dc.identifier.uri | http://hdl.handle.net/20.500.12281/10608 | |
| dc.description | A research project report submitted to the Department of Chemistry in partial fulfillment of the requirements for the award of the Degree of Bachelor of Science (physical) at Makerere University. | en_US |
| dc.description.abstract | This project was aimed at synthesizing and characterizing new and stable complexes that include bimetallic mixed-ligand complexes [Co(en)2][Co(SCN)4], [Zn(en)2][Co(SCN)4] and [Zn(An)6]3[Fe(SCN)6]2. The synthesized compounds are important in the chemical and biological industry. All the complexes were obtained almost immediately after mixing of the component metal complex solution. [Zn(An)6]3[Fe(SCN)6]2 appeared as a white fine powder, [Zn(en)2][Co(SCN)4] formed as green crystals. The synthesized trinitrotriammine cobalt (III) Compound formed the two possible products as stated in literature (yellow needles and yellow-brown compound) (MacDermott, 1968). The UV-visible spectra of aqueous solutions of bimetallic complexes show a maximum absorbance at a wavelength of 980nm due to the d→d transition of metal ion. The visible spectra of aqueous solutions of the polyoxometalates show a maximum absorbance at a wavelength of 400nm due to the f→f transitions. An aqueous solution of trinitrotriammine cobalt (III) shows a maximum absorbance at a wavelength of 350nm due to the eg← t2g transitions. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Makerere University | en_US |
| dc.subject | Trinitrotriammine cobalt (III) | en_US |
| dc.subject | Polyoxometalates (POM) | en_US |
| dc.subject | UV-visible spectra | en_US |
| dc.subject | Bimetallic mixed-ligand complexes | en_US |
| dc.title | Synthesis, characterization of stable cyano, thiocyanate bridged complexes and Polyoxometalate Inorganic fragments. | en_US |
| dc.type | Thesis | en_US |
